How to Test for Cations (Edexcel IGCSE Science)
Exam board Pearson Edexcel · IGCSEUpdated 2026-02-10
Tests for Cations
Spec point —
6.18
- Metal cations in aqueous solution can be identified by the colour of the precipitate they form on addition of sodium hydroxide
- If only a small amount of NaOH is used then normally the metal hydroxide precipitates
- The table below contains the results for each of the cations included in the syllabus
- If a precipitate is formed from NaOH then the hydroxide is insoluble in water
| Metal ion | Effect of adding NaOH |
|---|---|
| Cu2+ | Light blue precipitate formed |
| Fe2+ | Green precipitate formed |
| Fe3+ | Brown precipitate formed |
| NH4+ | Ammonia gas is produced which turns damp red litmus paper blue |
Exam Hint Sometimes you may not see much of a precipitate because the cation you are testing is present is very small amounts. However, every a slight cloudiness or colour change can indicate a positive test result.
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